Composite
Propellants

Composite propellants are heterogeneous mixtures of fuels and finely divided oxidizers bound by a viscous binder. Typical applications include solid rocket motors, satellite kick stages, and booster motors for cruise-missile launches.

Propellant Ingredient

FUNCTION

Specification

Aluminum Powder

Fuel

MIL-A-82728 (OS)

Aluminum Powder

Fuel

MIL-A-82728 (OS)

Ammonium Perchlorate

NH₄ClO₄ (ammonium perchlorate) is sold in 90, 200 and 400 µm particle sizes (other sizes possible). When blended with a binder and fuels like powdered aluminum, it can burn continuously even at much lower-than-atmospheric pressures, making it a common choice for rocket propellants.

Oxidizing Component

MIL-A-192B MIL-A-82667/2 (OS) MIL-A-82667/1 (OS) MIL-A-23946 (WEP) MIL-A-23948 (AS)

Ammonium Perchlorate

NH₄ClO₄ (ammonium perchlorate) is sold in 90, 200 and 400 µm particle sizes (other sizes possible). When blended with a binder and fuels like powdered aluminum, it can burn continuously even at much lower-than-atmospheric pressures, making it a common choice for rocket propellants.

Oxidizing Component

MIL-A-192B MIL-A-82667/2 (OS) MIL-A-82667/1 (OS) MIL-A-23946 (WEP) MIL-A-23948 (AS)

Butacene

Binder

Butacene

Binder

Carboxyl-terminated polybutadiene (CTPB) is a linear synthetic rubber frequently used as a high-performance binder in composite propellant formulations.

Binder (synthetic)

MIL-PRF-23942A (AS)

Carboxyl-terminated polybutadiene (CTPB) is a linear synthetic rubber frequently used as a high-performance binder in composite propellant formulations.

Binder (synthetic)

MIL-PRF-23942A (AS)

Catocene (2,2-Bis-Ethylferrocenyl Propane)

Catalyst (iron-based; >1 inch/sec burn rate)

Catocene (2,2-Bis-Ethylferrocenyl Propane)

Catalyst (iron-based; >1 inch/sec burn rate)

Di-(2-Ethylhexyl) Adipate (DEHA)

Plasticizer

DOD-D-23443B

Di-(2-Ethylhexyl) Adipate (DEHA)

Plasticizer

DOD-D-23443B

Di-(2-Ethylhexyl) Sebacate

Plasticizer

MIL-D-10692

Di-(2-Ethylhexyl) Sebacate

Plasticizer

MIL-D-10692

Dimeryl Diisocyanate (DDI)

Dimeryl diisocyanate (DDI-1510) is the preferred curative for low-molecular-weight HTPB polymer propellant formulations. This high-molecular-weight isocyanate features a 36-carbon aliphatic backbone, low toxicity, and low water sensitivity, and it also acts as a burn-rate catalyst

Curing agent

MIL-C-85498 (AS) Type I MIL-D-82675 (OS)

Dimeryl Diisocyanate (DDI)

Dimeryl diisocyanate (DDI-1510) is the preferred curative for low-molecular-weight HTPB polymer propellant formulations. This high-molecular-weight isocyanate features a 36-carbon aliphatic backbone, low toxicity, and low water sensitivity, and it also acts as a burn-rate catalyst

Curing agent

MIL-C-85498 (AS) Type I MIL-D-82675 (OS)

Dioctyl Adipate

Plasticizer

MIL-D-85494

Dioctyl Adipate

Plasticizer

MIL-D-85494

Dioctyl Phthalate

Plasticizer

MIL-D-38705

Dioctyl Phthalate

Plasticizer

MIL-D-38705

Dioctyl Sebacate (DOS)

Plasticizer

CAS: 122-62-3

Dioctyl Sebacate (DOS)

Plasticizer

CAS: 122-62-3

Hydroxyl Terminated Polybutadiene (HTPB)

HTPB is an outstanding binder for solid rocket propellants, delivering a robust yet elastic fuel matrix. It is also used as the solid component in hybrid rockets paired with nitrous oxide (N₂O). The R-45M grade of HTPB is the premium military binder, offering low-temperature flexibility, superior metal adhesion, and excellent filler dispersion.

Binder (synthetic)

MIL-H-85497

Hydroxyl Terminated Polybutadiene (HTPB)

HTPB is an outstanding binder for solid rocket propellants, delivering a robust yet elastic fuel matrix. It is also used as the solid component in hybrid rockets paired with nitrous oxide (N₂O). The R-45M grade of HTPB is the premium military binder, offering low-temperature flexibility, superior metal adhesion, and excellent filler dispersion.

Binder (synthetic)

MIL-H-85497

Isodecyl Pelargonate

Plasticizer

AS 2328

Isodecyl Pelargonate

Plasticizer

AS 2328

Isophorone Diisocyanate (IPDI)

Curing agent

MIL-C-85498 (AS) Type II WS-16305C

Isophorone Diisocyanate (IPDI)

Curing agent

MIL-C-85498 (AS) Type II WS-16305C

Isophthaloyl bis(2-methylaziridine) (DIB-752)

Binder

Isophthaloyl bis(2-methylaziridine) (DIB-752)

Binder

Neutral polymeric bonding agent (NPBA)

Binder

Neutral polymeric bonding agent (NPBA)

Binder

Polybutadiene Acrylonitrile (PBAN)

Binder

Polybutadiene Acrylonitrile (PBAN)

Binder

Triphenyl Bismuth

Cure catalyst, bonding and accelerating agent

MIL-T-82825 MIL-T-70681 WS-20883

Triphenyl Bismuth

Cure catalyst, bonding and accelerating agent

MIL-T-82825 MIL-T-70681 WS-20883

Bonding Agents for Composite Propellants

Bonding Agent

FUNCTION

Specification

1,1'-Isophthaloyl Bis[2-Methylaziridine

Bonding agent for Ammonium Perchlorate in polybutadiene matrices (752)

1,1'-Isophthaloyl Bis[2-Methylaziridine

Bonding agent for Ammonium Perchlorate in polybutadiene matrices (752)

MAPO (tris[1-(2-methyl) aziridinyl] phosphine oxide)

Curing agent for CTPB pre-polymers and a bonding agent for HTPB pre-polymers.

DOD-T-82666A

MAPO (tris[1-(2-methyl) aziridinyl] phosphine oxide)

Curing agent for CTPB pre-polymers and a bonding agent for HTPB pre-polymers.

DOD-T-82666A

Neutral Polymeric Bonding Agents (NPBA)

Bonding agent for composite rocket propellants

Neutral Polymeric Bonding Agents (NPBA)

Bonding agent for composite rocket propellants

TEPAN (Tetra-ethylenepentamine acrylnitrile)

Bonding agent

TEPAN (Tetra-ethylenepentamine acrylnitrile)

Bonding agent

TEPANOL (Tetra-ethylenepentamine acrylnitrile glycidol)

Liquid bonding agent and curative (878)

MIL-T-82824

TEPANOL (Tetra-ethylenepentamine acrylnitrile glycidol)

Liquid bonding agent and curative (878)

MIL-T-82824

Trimesol-1(2 ethyl) aziridine

Trifunctional aziridine amide curing agent (868)

Trimesol-1(2 ethyl) aziridine

Trifunctional aziridine amide curing agent (868)